The main thrust of this paper is to examine the different perspective that focuses on the application of artificial intelligence (AI) and blockchain technology on educational sustainability. It also discusses how the synergy between AI and blockchain technology transforms the educational landscape. The study goes beyond summarising the existing research; it evaluates, compares, and interprets the strengths, weaknesses, assumptions, and implications of prior studies. Articles gathered were examined for review from 2017 to 2025 to highlight the latest technological development in AI and blockchain applications in educational settings. Key findings revealed that the synergy between AI and blockchain technology is promising despite the scarcity of studies integrating these two domains. These technologies have proved to address the difficulties and challenges in academic institutions in terms of transparency, individualised learning, accessibility, data security, and the cost-effective utilisation of learning resources. Conclusions derived from the examination of the literature reveal that the collaboration between AI and blockchain technology will result in favourable outcomes. However, challenges were also prevalent in AI and blockchain implementation. Recommendations suggest that the acceptance and growth of AI and blockchain utilisation in the education sector require collaborative partnerships among stakeholders such as academic institutions, government agencies, technological companies, experts, and other related participants. This enables for a cohesive environment that encourages the application of AI and blockchain for enhanced and sustainable learning and innovation.