This study explores the impact of scouting on character formation and volunteerism among Eagle Scouts, focusing on the core values of MakaDiyos, Makatao, Makakalikasan, and Makabansa. It aims to determine how these values influence the level of volunteerism and whether Scouting activities contribute to students’ character development. Utilizing a mixed-method approach, the study gathered data through surveys and interviews with Eagle Scouts who achieved the highest rank in the Scouting program. Findings revealed that Makabansa (patriotism) was the most prominent value among the respondents. Additionally, a significant relationship was found between the level of Eagle Scout qualities and volunteerism, particularly in their motivation to serve. The results highlight how Scouting fosters a strong sense of civic duty and leadership among students. However, the study is limited to a specific group of Eagle Scouts, and further research is recommended to examine its broader impact across different educational settings. These findings suggest the need for training programs, workshops, or curriculum integration that support character formation, citizenship, and leadership development in alignment with the DepEd Core Values. Incorporating Scouting principles into the K–12 curriculum could enhance students’ personal growth, social responsibility, and overall well-being.